| Blignaut | J N | | Member of the late Legislative Assembly, Orange River Colony.
42 of 580 awards | Unknown |
| Blond | R H | Lt Col | CRE, Pretoria District
40 of 580 awards | Staff |
| Bok | W E | | Interpreter to National Convention. Secretary and Private Secretary to the Union PM. Clerk of the Union Education Council
43 of 580 awards | Unknown |
| Bolt | F W | | Member of the late Legislative Assembly, Orange River Colony
44 of 580 awards | Unknown |
| Bosman | Hendrik J | | Member of the Union House of Assembly.
45 of 580 awards | Unknown |
| Botha | Christiaan L | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
46 of 580 awards | Unknown |
| Botha | Louis | General | PM and Minister of Agriculture, Union of South Africa. Member of the Union House of Assembly.
47 of 580 awards | Unknown |
| Botha | Mrs Louis | | Wife of General Botha
48 of 580 awards | Unknown |
| Botha | R P | | Black Rod, Union Parliament
49 of 580 awards | Unknown |
| Brain | Thos P | | Member of the late Legislative Assembly, Orange River Colony. Member of the Union House of Assembly.
50 of 580 awards | Unknown |
| Brammer | C | | Member of the late Legislative Assembly, Transvaal
51 of 580 awards | Unknown |
| Brand | Robert H | | Late Secretary to Railway Board, Central SA Railways
52 of 580 awards | Unknown |
| Brebner | William J C | | Member of the late Legislative Council, Orange River Colony. Member of the Union Senate.
53 of 580 awards | Unknown |
| Briggs | Herbert | | Member of the late Legislative Assembly, Transvaal
54 of 580 awards | Unknown |
| Brookes | A Herbert | | Member of the late House of Assembly, Cape of Good Hope
55 of 580 awards | Unknown |
| Brown | Daniel M | | Member of the late House of Assembly, Cape of Good Hope. Member of the Union House of Assembly.
57 of 580 awards | Unknown |
| Brown | H Clifton | Lt Col | OC 12th Lancers
56 of 580 awards | 12th (The Prince of Wales's Royal) Lancers |
| Brown | William | | Member of the late House of Assembly, Cape of Good Hope
58 of 580 awards | Unknown |
| Browne | Albert | | Member of the late Legislative Council, Orange River Colony
59 of 580 awards | Unknown |
| Brunner | Ernest A | | Member of the late Legislative Assembly, Natal
60 of 580 awards | Unknown |
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