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Well, there were certainly a number of foreign volunteers who fought with Boer forces from both of the republics during the war, the museum in Bloemfontein would be worth contacting, they have an on line, searchable data base and I know that there will be a number of members of this forum in South Africa who will be able to assist you further.

The War Museum in Bloemfontein is here: www.wmbr.org.za/view.asp?pg=research&pgs...tabases&head1=Search

Also try familysearch.org they have lots of South African genealogical records.